In "Off Grid Mode" when using AC Charge Mode and the "AC Charge Based On" setting is set to "Time+SOC/Volt", It will switch to using the utility power for the entire window and not use the battery. It will charge the battery if the SOC falls below your set level.
Switching the "AC Charge Based On" setting to "SOC/Volt" does allow using the battery in this window but the charging will happen outside of the AC Charge window. The only way to prevent this is to set "Peak Saving Mode" to prevent charging over the entire remaining Working mode as shown in the graph below.


